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铅酸蓄电池板极固化过程中板栅表面腐蚀变化过程

 

铅酸蓄电池固化过程中板栅表面腐蚀的变化固化过程中板栅表面腐蚀的变化。特别在板栅表面与活性物质接触的界面要通过固化形成一层腐蚀膜,固化过程要在高温高湿下长达24 72h 的周期。在这种情况下,金属的氧化会加速,腐蚀过程会在板栅表面形成氧化铅层,这一氧化层与固化后的铅膏骨架直接提供接触。对正极而言,在化成时先是腐蚀层被氧化成为PbOn(n>l)及PbO2然后则是固化铅膏开始氧化。同样对于负极而言,腐蚀层首先被还原,然后才是固化铅膏。
板栅中铅的氧化过程或固化过程中板栅表面形成腐蚀层是一个极为重要的过程,也是活性物质能够与板栅结合得紧密牢实的本质原因与主要原因。板栅表面氧化后的氧化铅沉积在板栅表层,生长进人铅膏.由此在铅膏与板栅表面之间创建起一个非常牢固的联接,确保此后活性物质紧密附着在板栅上,不脱落活性物质。披覆铅膏的板栅在固化过程中会发生失重变化,在板栅/铅膏内表面上发生固化效应的过程。以4cmZ 的极板(板栅合金是Pb-1.6%Sb0.1%As)双面涂膏。

高温固化腐蚀层厚,有很牢固的腐蚀层/正极活性物质间良好的接触.因此形成一层适当性能的腐蚀层是极板固化的重要目的,高温固化更能促成这一目的。

The curing process of lead-acid battery grid surface corrosion changes in curing process of grid surface corrosion changes. Especially in the grid surface in contact with the active material interface through curing to form a layer of corrosion film, curing process at high temperature and high humidity for 24 72h cycle. In this case, oxidation of the metal will accelerate the corrosion process, in the grid is formed on the surface of lead oxide layer, the oxide layer and cured paste skeleton provides direct contact. On the positive, in the form of first is corrosion layer is oxidized to PbOn ( n>l ) and PbO2 then is cured paste oxidation. Similarly for negative electrode, corrosion layer is first reduction, and then curing the paste.

Plate gate in the oxidation processes of lead or curing process grid corrosion layer formed on the surface is a very important process, but also the active substances can and grid with tightly hold the essence reasons and the main reasons. Grid surface after oxidation of lead oxide is deposited in the grid surface, growing into the paste. The paste and grid surface is created between a very strong connection, ensure thereafter active substance is closely attached to the grid, not shedding of active material. Drape paste plate gate in the curing process can occur in a loss, in the grid / paste on the inside surface of solidified effect process. With 4cmZ plate ( plate grid alloy is Pb-1.6%Sb0.1%As ) double side paste coating.

High temperature curing corrosion layer thickness, have very strong corrosion layer / cathode active material of good contact. Thus forming a layer of appropriate properties of corrosion layer is the important objective of plate curing, high temperature curing can contribute to this purpose.

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